The water does a number of things:
- It shields the radiation from the spent fuel from harming anyone.
- The water is recirculated to keep the fuel rods in a cooling mode
There are some reports that the pool in #2 and/or #4 are damaged (leaking water) or that they were neglected and the water boiled off (partially or otherwise). There's no verification of this however. Ultimately this could be a much bigger issue than the core reactor because recooling them could be difficult (too hot). These pools contain a lot of spent fuel rods and if they heat up they can melt. If they melt they'll sink to the bottom of the pool and be in such a dense, close packed configuration that they could go critical and start generating heat again. This would be bad. But as of yet I don't see any confirmation other than some reports that #4 had a fire that some are suggesting was started by the spent fuel rods igniting and/or producing hydrogen and detonating.
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